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Aromaticity explain by Craig's rule






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  Order  Stability and Resonance Energy:-  Aromatic > Homoaromatic > Antiaromatic > Nonaromatic

   Aromaticity:- in Organic Chemistry, the Aromaticity is a property of Cyclic, planar structure with a ring of resonance bonds that gives the increased stability compared to other geometric with the same set of atoms. Aromatic compounds are very stable, and they do not break apart easily to react with other compounds. 

 Antiaromatic:- it is also a Cyclic molecule with a pi-electron system but there has higher energy due to the presence of 4n delocalized electrons in it. And Antiaromatic compounds are highly unstable and highly reactive in nature.

 Nonaromatic:- nonaromatic are every other molecules that fails one of these conditions (i.e., Cyclic, planar, conjugation and 4n or (4n+2) number of delocalized electrons, so anyone of these conditions is not fulfill, then the molecule is called non Aromatic compound).

Quasi-aromatic:- Quasi-aromatic compounds are those in which the charges are present on the ring/molecule, and they take a part of Aromaticity of the compound.

Homoaromaticity:- in Organic Chemistry, it refers to a special type of Aromaticity in which conjugation is interrupted by a single sp³ hybridized carbon atom. 
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Barton Reaction, organic Photochemistry

Barton reaction mechanism
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All Applications are collection from international journal papers


 At a glance:- The Barton reaction is an organic photochemical reaction that involves the photolysis of an alkyl nitrite to form a nitroso alcohol.
     Discover:- in 1960, this reaction is named for its discoverer, Nobel Laureate Sir Derek Barton.
     Photolysis:- it is a Chemical reaction in which a  Chemical compound that is broken down by photons. It is defined as the interaction of photons with the target molecules.
 
The Barton reaction involves a homolytic RO--NO bond cleavage by the abstraction of delta- Hydrogen and combination of two free radical, finally tautomerization can takes place to form an oxime species



#Animation | Beckmann Rearrangement & Fragmentation

Full PDF Book of Organic Chemistry written by Clayden, 2nd edition

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